Introducing a new radical trifluoromethylation reagent.
نویسندگان
چکیده
Perfluoro-3-ethyl-2,4-dimethyl-3-pentyl radical (PPFR) is a persistent radical stable at room temperature, but easily decomposes at 90 °C to produce a CF3 radical which is able to react with a variety of aromatic compounds to afford the corresponding trifluoromethyl derivatives, usually as mixtures of regioisomers in good to excellent overall yields.
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عنوان ژورنال:
- Chemical communications
دوره 51 27 شماره
صفحات -
تاریخ انتشار 2015